自然科学版 英文版
自然科学版 英文版
自然科学版 英文版

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中南大学学报(英文版)

Journal of Central South University

Vol. 20    No. 2    February 2013

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Layer by layer synthesis of Sn-Co-C microcomposites and their application in lithium ion batteries
ZHOU Xiang-yang(周向阳), ZOU You-lan(邹幽兰), Yang Juan(杨娟),
XIE Jing(谢静), WANG Song-can(王松灿)

School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China

Abstract:Alloy anodes were studied for pursuing Sn-based microcomposite synthesis, assembly and performance for lithium ion batteries. The self-assembled Sn-Co-C composites with nano-scaled microstructures were prepared via solution method and carbothermal technology. The morphology and physical structure were investigated with scanning electron microscope (SEM) and X-ray diffraction (XRD). The as-prepared materials were assembled to half cell coin for the purpose of discussing the galvanostatic cycling, cyclic voltammetry and rate-capability performance. Results reveal that nanoscaled CoSn2 alloys covered with Sn and C layer by layer are wrapped by cross-linked porous carbon network to form spherical microstructure. This distinguishing feature of Sn-Co-C composites provides a possible solution to the problems of Sn particle aggregation and poor electron transport, and has strong effect on improving electrochemical performance.

 

Key words: Sn-Co-C composite; hydrolysis; carbothermal technology; electrochemical performance; lithium ion battery

中南大学学报(自然科学版)
  ISSN 1672-7207
CN 43-1426/N
ZDXZAC
中南大学学报(英文版)
  ISSN 2095-2899
CN 43-1516/TB
JCSTFT
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